CDOM absorption properties of natural water bodies along extreme environmental gradients

We present absorption properties of colored dissolved organic matter (CDOM) sampled in six different water bodies along extreme altitudinal, latitudinal, and trophic state gradients. Three sites are in Norway: the mesotrophic Lysefjord (LF), Samnangerfjord (SF), and Røst Coastal Water (RCW); two sites are in China: the oligotrophic Lake Namtso (LN) and the eutrophic Bohai Sea (BS); and one site is in Uganda: the eutrophic Lake Victoria (LV). The site locations ranged from equatorial to subarctic regions, and they included water types from oligotrophic to eutrophic and altitudes from 0 m to 4700 m. The mean CDOM absorption coefficients at 440 nm [ a CDOM (440) aCDOM(440) ] and 320 nm [ a CDOM (320) aCDOM(320) ] varied in the ranges 0.063–0.35 m −1 −1 and 0.34–2.28 m −1 −1 , respectively, with highest values in LV, Uganda and the lowest in the high-altitude LN, Tibet. The mean spectral slopes S 280−500 S280−500 and S 350−500 S350−500 were found to vary in the ranges of 0.017–0.032 nm −1 −1 and 0.013–0.015 nm −1 −1 , respectively. The highest mean value for S 280−500 S280−500 as well as the lowest mean value for S 350−500 S350−500 were found in LN. Scatter plots of S 280−500 S280−500 versus a CDOM (440) aCDOM(440) and a CDOM (320) aCDOM(320) values ranges revealed a close connection between RCW, LF, and SF on one side, and BS and LV on the other side. CDOM seems to originate from terrestrial sources in LF, SF, BS, and LV, while RCW is characterized by autochthonous-oceanic CDOM, and LN by autochthonous CDOM. Photobleaching of CDOM is prominent in LN, demonstrated by absorption towards lower wavelengths in the UV spectrum. We conclude that high altitudes, implying high levels of UV radiation and oligotrophic water conditions are most important for making a significant change in CDOM absorption properties.publishedVersio

Quantifying the impacts of groundwater abstraction on Ganges river water infiltration into shallow aquifers under the rapidly developing city of Patna, India

Study region Patna is located on the southern bank of the River Ganges in Bihar, India. Rapid population growth over the past few decades has driven an increase in groundwater abstraction from aquifers under the city. Study focus This study exeplores the pumping-induced water exchange between the River Ganges and groundwater under transient conditions between 2009 and 2015, using a numerical simulation. The deterministic water exchange model within an uncertainty quantification was used to reveal the controlling factors affecting river water infiltration. New hydrological insights for the region Modelling reveals that under baseline (eno pumping) conditions, the dominant (~ 91% of the year) flow direction is from the aquifer to the river, which reverses (~ 9% of the year) when the river stage is high. When a municipal pumping well is implemented, river water infiltration into the aquifer increases to 68% of the year. The groundwater pumping rate is found to be the most important factor affecting the river water infiltration, whilst the groundwater table level is most sensitive to the well distance from the river, followed by pumping rate. Optimizing the location, depth and pumping rate of new wells in the area could mitigate fluvial contamination of the aquifer and help maintain groundwater levels

Validation of SO2 retrievals from the Ozone Monitoring Instrument (OMI) over NE China

The Ozone Monitoring Instrument (OMI) launched on the NASA Aura satellite in July 2004 offers unprecedented spatial resolution, coupled with contiguous daily global coverage, for space-based UV measurements of sulfur dioxide (SO2). We present a first validation of the OMI SO2 data with in-situ aircraft measurements in NE China in April 2005. The study demonstrates that OMI can distinguish between background SO2 conditions and heavy pollution on a daily basis. The noise (expressed as the standard deviation, σ) in the PBL SO2 data is ~1.5DU (Dobson Unit, 2.691016 molecules/cm2) for instantaneous field of view (IFOV) data. By looking at the pristine South Pacific under optimal conditions we have determined that temporal and spatial averaging can improve the resolution of the instrument to σ ~ 0.3 DU; the long term average over this remote location was within 0.1 DU of zero. Under polluted conditions, however, Collection 2 data are higher than aircraft measurements by a factor of two in most cases. Parameterization of the airmass factor (AMF) appears to enhance the accuracy of the SO2 data. Improved calibrations of the radiance and irradiance data (Collection 3) result in better agreement with aircraft measurements on polluted days. The re-processed and AMF-corrected Collection 3 data still show positive bias and sensitivity to UV absorbing aerosols. The difference between the in situ data and the OMI daily PBL SO2 measurements within 30 km of the aircraft profiles was about 1 DU, equivalent to ~5 ppb from 0 to 3000 m altitude. Quantifying the SO2 profile and spectral dependence of aerosol absorption between 310 and 330 nm are critical for accurate estimates of SO2 from satellite UV measurements

Emerging organic contaminants in the River Ganga and key tributaries in the middle Gangetic Plain, India: characterization, distribution & controls

The presence and distribution of emerging organic contaminants (EOCs) in freshwater environments is a key issue in India and globally, particularly due to ecotoxicological and potential antimicrobial resistance concerns. Here we have investigated the composition and spatial distribution of EOCs in surface water along a ∼500 km segment of the iconic River Ganges (Ganga) and key tributaries in the middle Gangetic Plain of Northern India. Using a broad screening approach, in 11 surface water samples, we identified 51 EOCs, comprising of pharmaceuticals, agrochemicals, lifestyle and industrial chemicals. Whilst the majority of EOCs detected were a mixture of pharmaceuticals and agrochemicals, lifestyle chemicals (and particularly sucralose) occurred at the highest concentrations. Ten of the EOCs detected are priority compounds (e.g. sulfamethoxazole, diuron, atrazine, chlorpyrifos, perfluorooctane sulfonate (PFOS), perfluorobutane sulfonate, thiamethoxam, imidacloprid, clothianidin and diclofenac). In almost 50% of water samples, sulfamethoxazole concentrations exceeded predicted no-effect concentrations (PNECs) for ecological toxicity. A significant downstream reduction in EOCs was observed along the River Ganga between Varanasi (Uttar Pradesh) and Begusarai (Bihar), likely reflecting dilution effects associated with three major tributaries, all with considerably lower EOC concentrations than the main Ganga channel. Sorption and/or redox controls were observed for some compounds (e.g. clopidol), as well as a relatively high degree of mixing of EOCs within the river. We discuss the environmental relevance of the persistence of several parent compounds (notably atrazine, carbamazepine, metribuzin and fipronil) and associated transformation products. Associations between EOCs and other hydrochemical parameters including excitation emission matrix (EEM) fluorescence indicated positive, significant, and compound-specific correlations between EOCs and tryptophan-, fulvic- and humic-like fluorescence. This study expands the baseline characterization of EOCs in Indian surface water and contributes to an improved understanding of the potential sources and controls on EOC distribution in the River Ganga and other large river systems